Synthesis of carbon nanotube-Fe-Al2O3 nanocomposite powders by selective reduction of different Al1.8Fe0.2O3 solid solutions

Carbon nanotubes-Fe-alumina nanocomposites. Part I: influence of the Fe content on the synthesis of powders

Oxides based on a-alumina and containing various amounts of Fe (2, 5, 10, 15 and 20 cat%) were prepared by decomposition and calcination of the corresponding mixed-oxalates. Selective reduction of the oxides in a H2±CH4 atmosphere produces nanometric Fe particles which are active for the in-situ nucleation and growth of carbon nanotubes. These form bundles smaller than 100 nm in diameter and se...

Influence of the composition of a H2-CH4 gas mixture on the catalytic synthesis of carbon nanotubes-Fe/Fe3C-Al2O3 nanocomposite powders

Carbon nanotubes-Fe-Alumina nanocomposites. Part II: microstructure and mechanical properties of the hot-Pressed composites

Carbon nanotubes±Fe±Al2O3 massive composites have been prepared by hot-pressing the corresponding composite powders, in which the carbon nanotubes are arranged in bundles smaller than 100 nm in diameter and several tens of micrometers long, forming a web-like network around the Fe±Al2O3 grains. In the powders, the quantity and the quality of the carbon nanotubes both depend on the Fe content (2...

Carbon nanotube-metal-oxide nanocomposites: microstructure, electrical conductivity and mechanical properties

Carbon nanotube–metal–oxide composites (metal=Fe, Co or Fe/Co alloy; oxide=Al2O3, MgO or MgAl2O4) have been prepared by hot-pressing the corresponding composite powders, in which the carbon nanotubes, mostly single or double-walled, are very homogeneously dispersed between the metal–oxide grains. For the sake of comparison, ceramic and metal–oxide nanocomposites have also been prepared. The mic...

Synthesis of TiC-Al2O3 Nanocomposite from Impure TiO2 by Mechanical Activated Sintering

In this research, the production possibility of TiC-Al2O3 nanocomposite, as a useful ceramic from commercially pure TiO2, aluminum powder and carbon black has been investigated. Routile (TiO2) with carbon black and aluminum were placed in a high energy ball mill and sampled during different milling times. Then, the activated powders were synthesized at different temperatures in an atmosphere co...